陈西良

• 1:黄河水利职业技术学院

摘要(Abstract)：

以聚乙烯吡咯烷酮(PVP)为表面活性剂,采用乙二醇(EG)溶剂热法在120℃合成了碘氧化铋(BiOI)纳米片组装的微结构。分析了样品的形貌、晶体结构、晶体生长方向和紫外-可见吸收光谱特征,探讨了溶剂组成对BiOI形貌的影响。研究结果表明,所制备的BiOI微米球尺寸均匀,形貌结构丰富,且具有良好的结晶性;PVP的加入可以使晶体的形貌和生长方向得到有效调控。同时,由于晶体的尺寸显著降低,导致紫外-可见吸收光谱的吸收边发生蓝移。

关键词(KeyWords)： 染料废水脱色;溶剂热法;碘氧化铋;微米球结构;聚乙烯吡咚烷酮

Abstract:

Keywords:

基金项目(Foundation): 河南省教育厅科学技术重点项目(14B150008);; 黄河水利职业技术学院科学技术项目(2013KXJS009)

作者(Author): 陈西良

DOI: 10.13681/j.cnki.cn41-1282/tv.2014.03.019

参考文献(References)：

• [1]Brown D,Hamberger B.Degradation of dye stuffs[J].Chemosphere,1987(16):1539-1553.
• [2]宋卫峰,倪亚明,何德文.电解法水处理技术的研究进展[J].化工环保,2001,21(1):11-15.
• [3]王娟,范迪.臭氧氧化法深度处理造纸废水试验研究[J].工业水处理,2009,29(1):33-35.
• [4]魏平玉,杨青林,郭林.卤氧化铋化合物光催化剂[J].化学进展,2009,21(9):1734-1741.
• [5]Henle J,Simon P,Frenzel A,et al.Nanosized BiOX(X=Cl,Br,I)particles synthesized in reverse microemulsions[J].Chem.Mater,2007(19):366-373.
• [6]Deng Hong,Wang Jun Wei,Peng Qing,et al.Controlled hydrothermal synthesis of bismuth oxyhalide nanobelts and nanotubes[J].Chem.Eur.J,2005(11):6519-6524.
• [7]Zhang Die Qing,Wen Mei Cheng,Jiang Bo,et al.Ionothermal synthesis of hierarchical BiOBr microspheres for water treatment[J].J.Hazard.Mater.2012,211-212:104–111.
• [8]Shi Xiao Jing,Chen Xi Liang,Chen Xin,et al.Solvothermal synthesis of BiOI hierarchical spheres with homogeneous sizes and their high photocatalytic performance[J].Mater.Lett,2012,68:296-299.
• [9]Cheng He Feng,Huang Bai Biao,Wang Ze Yan,et al.One-pot miniemulsion-mediated route to BiOBr hollow microspheres with highly efficient photocatalytic activity[J].Chem.Eur.J,2011(17):8039-8043.
• [10]Zhang Jun,Shi Feng Jun,Lin Jing,et al.Selfassembled 3-D architectures of BiOBr as a visible light-driven photocatalyst[J].Chem.Mater,2008(20):2937-2941.
• [11]刘红旗,顾晓娜,陈锋,等.BiOCl纳米片微球的制备及其形成机理[J].催化学报,2011,32(1):129-134.
• [12]Liu Hong,Cao Wei Ran,Su Yun,et al.Synthesis,characterization and photocatalytic performance of novel visible-light-induced Ag/BiOI[J].Appl.Catal.B:Environ,2012,111-112:271-279.